(Dimethyl sulfoxide-κO)bis(thiosemicarbazide-κ2N1,S)zinc dipicrate dimethyl sulfoxide solvate monohydrate

(Dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ2 N 1,S)zinc dipicrate dimethyl sulfoxide solvate monohydrate

The title complex, [Zn(CH(5)N(3)S)(2)(C(2)H(6)OS)](C(6)H(2)N(3)O(7))(2)·C(2)H(6)OS·H(2)O, is composed of a [Zn(thio-semi-carbazide)(2)(DMSO)](2+) cation (where DMSO is dimethyl sulfoxide), and two picrate anions. In the asymmetric unit, there is also a solvent mol-ecule of DMSO and a water mol-ecule of crystallization. In the cation, the Zn(II) atom is five-coordinated in a distorted square-pyr...

Bis[4-(4-chloro­phen­yl)-4-hydroxy­piperidinium] dipicrate dimethyl sulfoxide solvate

The asymmetric unit of the title salt solvate, 2C(11)H(15)ClNO(+)·2C(6)H(2)N(3)O(7) (-)·C(2)H(6)OS, contains two crystallographically independent 4-(4-chloro-phen-yl)-4-hydroxy-piperidinium cations, two picrate anions and a dimethyl sulfoxide solvent mol-ecule. In each cation, the piperidinium ring adopts a chair conformation. In the crystal structure, the cations, anions and solvent mol-ecules...

Trimesic acid dimethyl sulfoxide solvate: space group revision

The structure of the title solvate, C(9)H(6)O(6)·C(2)H(6)OS, was determined 30 years ago [Herbstein, Kapon & Wasserman (1978 ▶). Acta Cryst. B34, 1613-1617], with data collected at room temperature, and refined in the space group P2(1). The present redetermination, based on high-resolution diffraction data, shows that the actual space group is more likely to be P2(1)/m. The crystal structure co...

Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium

The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordin-ating through the O atom. The anionic saccharinate (sac; 1,1,3-trioxo-2,3-dihydro-1λ(6),2-benzothia-zol-2-ide) ligand coordin-ates through the ...

Clinical Considerations of Dimethyl Sulfoxide